What Is Acrylic Adhesive?
Acrylic adhesives are adhesives whose main ingredient is acrylic acid or its derivatives (methyl methacrylate, etc.).
They are classified into the first to third generations based on the presence or absence of chemical reactions during the curing process. Currently, the second generation (SGA: Second Generation Acrylic Adhesives), which involves a polymerization reaction during curing, is the most prevalent.
SGA includes two component types where the curing reaction occurs when the main and curing agents come into contact with each other. The first type is the one-component primer type, in which a primer is used instead of a curing agent, and curing occurs through heating. The second type is the two-component type, which is currently the most commonly used.
SGA exhibits excellent impact resistance, heat resistance, and water resistance, making it one of the most reliable structural adhesives with minimal degradation in adhesive properties even when subjected to heavy loads for extended periods.
Difference Between Acrylic Adhesives and Adhesives for Acrylic Resin
Although the names of these two types of adhesives are very similar, they have distinct properties. However, it is essential to note that both adhesives are referred to as “acrylic adhesives” in some cases.
Specifically, “acrylic adhesives,” the subject of this article, are adhesives that primarily contain acrylic acid and its derivatives, whereas “adhesives for acrylic resins” refer to bonding agents used to melt and join acrylic sheets, with entirely different adhesion principles and usage.
Uses of Acrylic Adhesives
Second-generation acrylic adhesives (SGA), currently the mainstream, are suitable for household and industrial applications, each serving various purposes. They are specifically useful for bonding the following substrates:
- Metals
- Thermoplastic resin
- Thermosetting resins
- Composite materials
Among these, two-component SGA excels at bonding different materials and large areas. It is employed, for example, in affixing motor magnets (permanent magnets) to stators in automobiles and bonding battery cells in electric vehicles.
SGA is also utilized as potting material for safeguarding electronic circuit boards. It finds applications in various other areas, including bonding plastics, metals, and tiles, as well as construction applications.
Principles of Acrylic Adhesives
Here is an overview of each generation of acrylic adhesives:
- First Generation: This type comprises acrylic monomers, acrylic oligomers, and curing agents, but no chemical reaction occurs during curing.
- Second Generation: It consists of almost the same composition as the first generation, but curing takes place through a polymerization reaction between the monomer and polymer. Compared to the first generation, it is characterized by superior adhesiveness, durability, and various other properties.
- Third Generation: Radical polymerization is initiated and cured by irradiating energy such as ultraviolet rays or electromagnetic waves. Second-generation acrylic adhesives (SGA), which are currently the mainstream, are classified into two components, one-component primer, and one-component types.
The two-component type comprises two components, A and B, with the primary ingredients being acrylic monomers and elastomers.
The difference in composition between the two liquids lies in Agent A, where cumene hydroperoxide is added as a polymerization initiator, and Agent B, where a reducing agent like a metal complex or thiourea derivative is included as a curing accelerator.
Mixing both solutions initiates a radical reaction and begins the curing of the acrylic monomer. Since the primary components of these two liquids are essentially the same, they are straightforward to mix, and even slight variations in the mixing ratio of the two liquids do not significantly affect the physical properties after curing. This ease of use is due to the fact that the mixing ratio of the two liquids does not need to be strictly 1:1.
The one-component primer type substitutes the hardener of the two-component type with a primer, and, like the two-component type, generates radicals and proceeds with curing. The one-component type contains a catalyst activated by heating and cures when heated.
SGA boasts features such as oil-surface adhesion, excellent resistance to shear and tension, and internal stress relaxation. However, acrylic adhesives containing methyl methacrylate have the drawback of emitting an acrylic odor.
Curing Time of Acrylic Adhesives
Acrylic adhesives cure through a chemical reaction, boasting extremely rapid curing times and robust adhesion. The typical curing time is approximately 5 minutes after application. However, when used to reinforce joints and prevent water leakage, it is necessary to allow for curing for about one day.
As a precaution when using the adhesive, it is advisable to wait briefly after application before clamping. This waiting period allows the adhesive components to disperse and permeate into the air and adhere to the material for proper curing and adhesion.
Waiting for a few minutes after application before clamping helps ensure proper adhesion and prevents volume shrinkage that occurs as the adhesive cures.
How to Remove Acrylic Adhesives
Due to their exceptional adhesive strength and durability, acrylic adhesives cannot be peeled off easily. Therefore, it is essential to choose a suitable method for removing acrylic adhesives based on their adhesive mechanism.
While the term “adhesion” is used to describe acrylic adhesives, they are technically a form of welding. A chemical reaction dissolves the adherend materials to form a single piece.
Organic solvents such as toluene and benzene are effective for removing solvent-based adhesives. These solvents contain components that dissolve plastics like acrylics. Organic solvents have the property of dissolving plastics and are effective in removing acrylic adhesives.
Once fully dissolved, removal can be challenging. In some cases, one adherend may need to be left in place while the other is physically destroyed. To avoid this, it is recommended to attempt solvent stripping as a first step.
What to Do When Acrylic Adhesives Turn White
When using acrylic adhesives whose main ingredient is cyanoacrylate, a white residue, known as “whitening,” may remain around the adherend.
To prevent this phenomenon, it is essential to eliminate dust and moisture from the adhesive surface and the surrounding area and select a low humidity work environment.
Using a curing accelerator that is less likely to cause whitening in advance is also a good practice. If whitening does occur, it can be removed through chemical removal using an organic solvent or physical removal using sandpaper.