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Nitrogen Dioxide

What Is Nitrogen Dioxide?

Nitrogen dioxide, a reddish-brown gas with a pungent odor, is a significant air pollutant produced primarily from combustion processes, notably in automobile engines. It’s involved in the formation of acid rain and ozone, posing health risks, especially to the respiratory tract.

Uses of Nitrogen Dioxide

It finds applications in analytical chemistry, manufacturing of nitrogen compounds, as a bleaching and nitrosating agent, and as an oxidizer in rocket fuels, notably used in historic space missions.

Properties of Nitrogen Dioxide

Nitrogen dioxide transitions from a reddish-brown gas to a yellow liquid and then to colorless dinitrogen tetroxide under varying temperatures, demonstrating its ability to absorb blue light and participate in photolysis. It is paramagnetic due to an unpaired electron.

Structure of Nitrogen Dioxide

With the chemical formula NO2, it exhibits C2v symmetry, showcasing bond lengths and angles intermediate between its cationic and anionic forms.

Other Information on Nitrogen Dioxide

1. Synthesis of Nitrogen Dioxide

Produced industrially by oxidizing ammonia or through the reaction of concentrated nitric acid with metals, nitrogen dioxide is also a byproduct of combustion and natural biological activity, contributing to urban air pollution.

2. Reactions of Nitrogen Dioxide

It’s involved in equilibrium with dinitrogen tetroxide, contributes to acid rain through its reaction with water, and reacts with sulfur dioxide to produce nitric oxide and sulfur trioxide.

3. Environmental Pollution Caused by Nitrogen Dioxide

Regulated under air pollution control laws, nitrogen dioxide levels have stabilized due to emission controls, yet concentrations near major roads frequently exceed environmental standards, highlighting ongoing challenges in air quality management.

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